Product ID:1507 PROPANE TANK PAINT, KRYLON HIGH HEAT (SUPDAT)
MSDS Date:09/01/1996
FSC:8010
NIIN:00N087749
MSDS Number: CHKCK

SHERWIN-WILLIAMS

31500 SOLON RD
SOLON, OH 44139
US

Emergency Phone: 216-566-2917

Info Phone: 800-247-3270

Cage: DO642

SHERWIN-WILLIAMS CO THE SPECIALTY DIV.

6709 SOLON, OH 44139-3908

Telephone: 216-292-7400

Cage: DO642

760.

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 14%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

760.

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: 6%

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM

7.1.

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM;125 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.9.

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 8%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM;150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.5.

CAS: 71-36-3

RTECS: EO1400000

Fraction By Weight: 1%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM, S, C

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

180.

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 38%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM;1000 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 44%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM;300 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (SARA

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 2%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM;75 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER;

CAS: 108-65-6

RTECS: AI8925000

Fraction By Weight: 7%

OSHA PEL N/K

ACGIH TLV: N/K

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 5.3%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

45.2% (WT);

RTECS: 9999999VO

APPARENT. OBTAIN MEDICAL ATTENTION.

RTECS: 9999999ZZ

TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVEL

RTECS: 9999999ZZ

ATTAINABLE IN THE WORKPLACE. RPTS HAVE ASSOC RPTD &

RTECS: 9999999ZZ

INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS

RTECS: 9999999ZZ

CONTAIN CHEM(S) KNOWN TO STATE OF CALIFORNIA TO

RTECS: 9999999ZZ

CONSULT NFPA CODE. CONTENTS UNDER PRESS. DO NOT

RTECS: 9999999ZZ

SUNLIGHT, RADIATORS, STOVES, HOT WATER & OTHER HEAT

RTECS: 9999999ZZ

INTERNALLY. KEEP OUT OF REACH OF CHILDREN. ADDN OF

RTECS: 9999999ZZ

SUBSTANTIALLY ALTER COMPOSITION & HAZS OF PROD. USE

RTECS: 9999999ZZ

CONT W/SKIN & EYES. THESE COATINGS MAY CONTAIN MATLS

RTECS: 9999999ZZ

PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING

RTECS: 9999999ZZ

LIMS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE
CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR
PROPER USE, VENT & PPE. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY
CAUSE NERV SYS DEPRESS. EXTREME OV EREXP MAY RSLT IN UNCON & POSS
DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF
EXCESSIVE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:EXPOS TO VAPS/SPRAY MISTS. REDNESS &
ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS.
CHRONIC:PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE EFTS TO LIVER,
URINARY, BLOOD-FORMING, CARDIOVASCULAR & REPRO SYSTEMS. METHYL
ETHYL KETONE MAY INCR NERV SYS EFTS OF OTHER SOLVS. RATS EXPOSED TO
(ING 13)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE
CONTAMINATED CLOHTING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGEST:GET MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:1%
Upper Limits:36.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF.
WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT)
Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. ISOLATE FROM HEAT, ELEC
EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO
EXTREME HEAT. APPLICATION TO HOT SURFS REQS (SUPP DATA)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE &
REMOVE W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NFPA CODE 30B - LEVEL 3 AEROSOLS.
CONTENTS ARE EXTREMELY FLAMM. KEEP AWAY FROM HEAT, SPKS & OPEN
FLAME. USE APPRVD BONDING & GROUNDING PROCS.
Other Precautions:VAPS WILL ACCUM READILY & IGNITE EXPLOSIVELY. DURING
USE & UNTIL ALL VAPS ARE GONE:KEEP AREA VENTED; DO NOT SMOKE;
EXTING ALL FLAMES, PILOT LIGHTS & HEATERS; TURN OFF STOVES, ELEC
TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. (ING 17)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR NIOSH APPRVD PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING
DRIED FILM, WEAR A NIOSH APPRVD DUST/MIST RESP FOR PROT (SUPDAT)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO INGS IS
MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS (SUPP DATA)
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:RESISTANT PAINTS. FIRE FIGHT PROC:PVNT PRESS
BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. RESP
PROT:AGAINST NON-VOLAT INGS. VENT:1910.94, 1910.107, 1910.108. EX
PLO HAZ:SPECIAL PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS
MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED (ING 12)

Boiling Pt:B.P. Text:<395F,<202C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.79
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON
MONOXIDE.

Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZ AS DEFINED
UNDER RCRA (40 CFR 261). WASTE MUST BE TESTED FOR IGNITABILITY TO
DETERMINE APPLIC EPA HAZ WASTE NUMBERS. DO NOT INCINERATE.
DEPRESSURIZE CNTNR. DISPOSE O F I/A/W FED, STATE & LOC REGS
REGARDINGPOLLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.